By Ian S. Longmuir
Advances in Polarography, quantity 2 covers the complaints of the second one overseas Congress held at Cambridge in 1959 in honor of the seventieth birthday of Professor Heyrovsky.
This quantity consists of 35 chapters and starts with extensive discussions at the theoretical and basic elements, in addition to pertinent equations in polarography. huge chapters are dedicated to the chemical and metallurgical functions of the strategy, with emphasis at the hint decision of convinced compounds. the rest chapters discover different program of particular polarographic method, similar to nicotinic acid, iso-benzpyrylium salts, and steel complicated research.
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Extra info for Advances in Polarography. Proceedings of the Second International Congress Held at Cambridge 1959
J . M. L o s : I h r e interessante B e o b a c h t u n g m ö g e n wir wohl als B e s t ä t i g u n g unserer B e h a u p t u n g ü b e r die K o n v e k t i o n a n m e r k e n . A CONTRIBUTION TO THE THEORY OF POLAROGRAPHIC CURRENTS, INFLUENCED BY AN ADSORPTION OF AN ELECTROINACTIVE SUBSTANCE B y J . W E B E R , J . K O U T E C K Y and J. KORYTA Institute of Physical Chemistry and Institute of Polarography, Czechoslovak Academy of Science, Prague T H E AIM of the present communication is to give a quantitative account of polarographic currents in the presence of an electroinactive substance A, which is adsorbed at the surface of the electrode and influences the electrode reaction of the electroactive depolariser present in the solution in both oxidised and reduced forms B, C.
Suzuki has concluded on t h e bases of experi mental results obtained b y discontinuously changing potential method t h a t 100 CsJ pH F I G . 2. Change of limiting current of ^-nitrosophenol with p H . the first step proceeds reversibly. H e has also found t h a t t h e slopes of linear plots of log (ii —l)fi vs. E are 30-34mV in acidic and neutral solu tions, which are in agreement with t h e theoretical consideration. The halfwave potential of t h e first wave ìEi is not equal t o t h e standard electrode potential of t h e first step Ei°.
N . J. Amer. Chem. Soc. 80, 2087, 1958. 24. GIERST L. Cinétique d'approche et réactions delectrodes irréversible. Inaugural Dissertation. Université Libre de Bruxelles. 25. MAJRANOVSKIJ S. G. Dokl. Akad. Nauk SSSR 120, 1294, 1958. 26. v. , and FASSBENDER H . Z. Elektrochem. 62, 834, 1958. 27. VOLKOVA V. Communication to t h e 2 n d Czechoslovak-Hungarian polarographic conference, Prague, 1958. 28. , and SMOLER I. Communication to the 2 n d Czechoslovak-Hungarian polaro graphic conference, Prague, 1958.
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